The Bayesian approach to an internally consistent thermodynamic database: theory, database, and generation of phase diagrams     

Niranjan D. Chatterjee  Ralf Krüger  Gerd Haller  Walter Olbricht 《Contributions to Mineralogy and Petrology》1998,133(1-2):149-168

An internally consistent thermodynamic dataset has been derived for 148 endmember phases (145 solids and 3 fluids) comprising the elements Li, Na, K, Be, Mg, Ca, Ti, Cr, Mn, Fe, Zn, Al, Si, C, H, and O. This has been achieved by simultaneous treatment of phase property (like standard enthalpy of formation, standard entropy, molar heat capacity, molar volume, thermal expansivity, bulk modulus etc.) and reaction reversal data by the Bayesian method. The theory underlying the approach, and the computational methods involved, are briefly outlined. (For the benefit of readers unfamiliar with inference statistics, the basic concepts of the Bayes method are also presented in such a way that they can be grasped intuitively.) Although not yet addressed, this method can be extended to refine the thermodynamic mixing properties of crystalline solutions. The sources of the input data, culled from the literature, are summarized in the Appendix. The resulting database is succinctly documented in this paper. It includes the enthalpies of formation and entropies, their uncertainties, and the correlation among them. The database allows calculation of P-T, T-X _CO2, P-X _CO2, and T-f _O2 sections, with error propagation into the computed phase diagrams on a routine basis. A user-friendly computer program has been written to generate such phase diagrams. It is public domain software. The software and the thermodynamic database (which includes a complete documentation of the thermodynamic data above and beyond those listed (Table 2, here) may be downloaded from the web site http://homepage.ruhr-uni-bochum.de/niranjan.chatterjee/Index.htm. Examples of computed phase diagrams are given to illustrate the quality of the data and the capabilities of the software. Received: 11 March 1998 / Accepted: 11 June 1998  相似文献   

Local stellar kinematics from Hipparcos data   总被引：1，自引：0，他引：1  

Walter Dehnen  & James J. Binney 《Monthly notices of the Royal Astronomical Society》1998,298(2):387-394

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An assessment of the use of stabilized coal and oil ash for construction of artificial fishing reefs: Comparison of fishes observed on small ash and concrete reefs   总被引：2，自引：0，他引：2  

Frederic E. Vose  Walter G. Nelson   《Marine pollution bulletin》1998,36(12):980-988

Fishes present on small artificial reefs located 2 km off the central east coast of Florida (USA) were surveyed to determine the acceptability of using stabilized oil and coal ash residue as a component material in construction of artificial fishing reefs. Species richness was not significantly different over 2.5 yr on stabilized oil and coal ash reefs compared to concrete control reefs. Of 19 species tested for significant differences in mean abundance, lane snapper was observed at significantly higher mean abundances on fossil-fuel ash reefs (stabilized oil ash/coal fly ash), while three reef species (hairy blenny, porkfish and gray snapper) were significantly more common on concrete control reefs. Further study is needed to determine whether contaminants (Cu, V, Ni and Zn) from stabilized ash blocks can cause abundance differences for some fishes. Plausible alternate explanations for the differences in mean abundance include both interspecific interactions (competition and predation) and differences in the attraction or retention of fish among reef replicates due to slight variations in reef dimensions.  相似文献   

Mass models of the Milky Way     

Walter Dehnen  & James Binney 《Monthly notices of the Royal Astronomical Society》1998,294(3):429-438

A parametrized model of the mass distribution within the Milky Way is fitted to the available observational constraints. The most important single parameter is the ratio of the scalelength R _d* of the stellar disc to R ₀. The disc and bulge dominate v _c( R ) at R ≲ R ₀ only for R _d,*/ R ₀≲0.3. Since the only knowledge we have of the halo derives from studies like the present one, we allow it to contribute to the density at all radii. When allowed this freedom, however, the halo causes changes in assumptions relating to R  ≪  R ₀ to affect profoundly the structure of the best-fitting model at R  ≫  R ₀. For example, changing the disc slightly from an exponential surface-density profile significantly changes the form of v _c( R ) at R  ≫  R ₀, where the disc makes a negligible contribution to v _c. Moreover, minor changes in the constraints can cause the halo to develop a deep hole at its centre that is not physically plausible. These problems call into question the proposition that flat rotation curves arise because galaxies have physically distinct haloes rather than outwards-increasing mass-to-light ratios.   The mass distribution of the Galaxy and the relative importance of its various components will remain very uncertain until more observational data can be used to constrain mass models. Data that constrain the Galactic force field at z ≳ R and at R  >  R ₀ are especially important.  相似文献   

Motion of a test particle in a nonstationary spherically symmetric gravitational field in flat space-time theory of gravitation     

Walter Petry 《Astrophysics and Space Science》1995,232(2):233-240

The previously studied 2-post-Newtonian approximation of the gravitational field of a nonstationary spherically symmetric star in flat space-time theory of gravitation is applied to the motion of a test particle in the orbit of the star. The orbit is different from the one of Einstein's general theory of relativity. A general formula for the deviation of the orbit from a circle is given. In the special case of a radially oscillating star, being homogeneous to Newtonian accuracy, the orbit of the test particle also oscillates radially with small amplitude about a fixed orbit (circle).  相似文献   

Potential and inductive electric fields in the magnetosphere during auroras     

Walter J. Heikkila  R.J. Pellinen  C.-G. Fälthammar  L.P. Block 《Planetary and Space Science》1979,27(11):1383-1389

During quiescent auroras the large-scale electric field is essentially irrotational. The volume formed by the plasma sheet and its extension into the auroral oval is connected to an external source by electric currents, which enter and leave the volume at different electric potentials and which supply sufficient energy to support the auroral activity. The location of the actual acceleration of particles depends on the internal distribution of electric fields and currents. One important feature is the energization of the carriers of the cross-tail current and another is the acceleration of electrons precipitated through relatively low-altitude magnetic-field-aligned potential drops.Substorm auroras depend on rapid and (especially initially) localized release of energy that can only be supplied by tapping stored magnetic energy. The energy is transmitted to the charged particle via electric inductive fields.The primary electric field due to changing electric currents is redistributed in a complicated way—but never extinguished—by polarization of charges. As a consequence, any tendency of the plasma to suppress magnetic-field-aligned components of the electric fields leads to a corresponding enhancement of the transverse component.  相似文献   

Dispersivity Estimates from a Tracer Experiment in a Sandy Aquifer     

Dirk Mallants  Armando Espino  Marijke Van  Hoorick  Jan Feyen  Noel Vandenberghe  Walter Loy 《Ground water》2000,38(2):304-310

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The carbon cycle and biogeochemical dynamics in lake sediments   总被引：30，自引：3，他引：27  

Walter E. Dean 《Journal of Paleolimnology》1999,21(4):375-393

The concentrations of organic carbon (OC) and CaCO3 in lake sediments are often inversely related. This relation occurs in surface sediments from different locations in the same lake, surface sediments from different lakes, and with depth in Holocene sediments. Where data on accumulation rates are available, the relation holds for organic carbon and CaCO3 accumulation rates as well. An increase of several percent OC is accompanied by a decrease of several tens of percent CaCO3 indicating that the inverse relation is not due to simple dilution of one component by another. It appears from core data that once the OC concentration in the sediments becomes greater than about 12%, the CO2 produced by decomposition of that OC and production of organic acids lowers the pH of anoxic pore waters enough to dissolve any CaCO3 that reaches the sediment-water interface. In a lake with a seasonally anoxic hypolimnion, processes in the water column also can produce an inverse relation between OC and CaCO3 over time. If productivity of the lake increases, the rain rate of OC from the epilimnion increases. Biogenic removal of CO2 and accompanying increase in pH also may increase the production of CaCO3. However, the decomposition of organic matter in the hypolimnion will decrease the pH of the hypolimnion causing greater dissolution of CaCO3 and therefore a decrease in the rain rate of CaCO3 to the sediment-water interface.  相似文献   

Seeing Conditions at Sutherland. Results of the 1992/93 seeing campaign     

Josef Gochermann  Walter F. Wargau  Claus Tappert  Theodor Schmidt-Kaler  Robert S. Stobie  Fred Marang  Greg Roberts  Francois G. van Wyk  Peter Rucks 《Experimental Astronomy》1999,9(1):1-15

In order to decide whether the seeing conditions at SAAO/Sutherland justify the erection of a 3.5 m telescope and also to compare Sutherland with the Gamsberg/Namibia site, a seeing campaign covering 15 months has been carried out. For direct comparison with the results of the seeing campaign at Gamsberg twenty years before the same QUESTAR telescope was employed. The seeing is determined by the scattering of the star-trail exposed on a film in the focal plane of the telescope. The campaign commenced in February 1992. Up to May 1993, data for 204 nights, that is 47.3% of the total number of nights, were collected. Due to wind speeds above 30 km h^-1, 25 out of the 204 nights were not considered in the final reduction. The useful 179 nights are evenly distributed over the campaign period. The median seeing value for the whole period is = 0.52. There are differences during the year: the best season gives = 0.42, the worst = 0.67. Each night was divided into three intervals, although data for each of the three intervals were not always available. Generally, there is an improvement in the seeing during the course of a night. The results are compared to the seeing values of Gamsberg/Namibia and ESO/La Silla.  相似文献   

40Ar/39Ar Thermochronology west of the Main Uralian fault, southern Urals, Russia     

U. A. Glasmacher  P. Reynolds  A. A. Alekseyev  V. N. Puchkov  K. Taylor  V. Gorozhanin  R. Walter 《International Journal of Earth Sciences》1999,87(4):515-525

West of the Main Uralian fault, the main suture in the southern Urals, ⁴⁰Ar/³⁹Ar apparent ages of amphibole, muscovite and potassium feldspar are interpreted as cooling ages. A fast exhumation of the metamorphic complex of Kurtinsky during Upper Carboniferous time is indicated by the small age difference (15 Ma) between cogenetic amphibole and muscovite. Differentiated movement in the footwall of the Main Uralian fault along strike is indicated by the age difference of 70 Ma between the metamorphic complexes of Kurtinsky (north) and Maksyutov (south). No Upper Paleozoic (Uralian) medium- to high-temperature event is recorded in ⁴⁰Ar/³⁹Ar data from the metamorphic complex of Beloretzk (MCB). An amphibole age of 718±5 Ma and the occurrence of mafic intrusions might signal the break-up of Rodinia and therefore indicate the rifting period followed by the separate movement of the "Beloretzk terrane". Muscovite ages of approximately 550±5 Ma, the unique pre-Ordovician tectonometamorphic evolution of the MCB and the Late Vendian sedimentary history of the western Bashkirian Megaanticlinorium (BMA) imply the existence of a Neoproterozoic orogeny at the eastern margin of Baltica. This orogeny might have been initiated by the accretion of the "Beloretzk terrane". The metamorphic grade of the overlain Silurian shales and the K/Ar microcline ages from the "Beloretzk terrane" give evidence for a new thermal event at approximately 370 Ma. A microcline age of 530–550 Ma obtained for the Vendian conglomerate in the western BMA suggests that a maximum temperature of approximately 200°C was reached in Cambrian or Vendian times. An orthoclase age (590–630 Ma) of the Vendian Zigan flysch deposits might be inherited from the eastern source area, the Cadomian orogen. An orthoclase age (910–950 Ma) from the Riphean Zilmerdak conglomerate coincides with a documented decrease in the subsidence rate of the Upper Riphean basin.  相似文献